Geochemistry of sediments and volcanic ash from Southcentral Alaska


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Resource Abstract:
Abstract: The subarctic Pacific Ocean and Bering Sea comprise the second-largest high nitrate, low chlorophyll region in the world, where primary production is limited by the availability of iron (Fe). To estimate the potential impact of different terrestrial aerosol Fe sources on marine ecosystems, we performed a suite of laboratory assessments following established protocols, including: 1) leaching with Milli-Q water, 2) sequential extractions, 3) complete acid digestions, 4) X-ray diffraction, and 5) grain size analysis. Measurements were performed on 20 fine-grained (<5 μm) glacier-derived sediments from Alaska and the Yukon, 2 fresh, never-wetted volcanic ashes (Redoubt 2009 and Pavlof 2016), and 6 weathered ashes (Redoubt and Augustine) which span the past ~8700 years. We compared results to published data on Asian desert-derived sediments, finding that the glacier-derived sediments have five times higher easily-reducible Fe (median 2.3 ± 0.6 wt. %) than desert-derived samples (0.49 ± 0.1 wt. %) and fourteen times higher easily-reducible Fe than fresh ash (0.16 ± 0.1 wt. %). In addition, fractional Fe solubility was higher in glacial sediment (median cumulative 0.31 ± 0.11% FeS) than volcanic ash (0.04 ± 0.02 % FeS). Glacial sediments also contained higher concentrations of bioactive metals including Co, Ni, Cu, Zn, Mo, Cd, and Pb. Inferred Fe availability increased with sample age, pointing to the ability of environmental weathering processes to change Fe geochemistry. Other Description: Koffman, B.G., Yoder, M.F., Methven, T., Hanschka, L., Sears, H.B., Saylor, P.L., Wallace, K.L., (submitted 2020). "Glacial dust surpasses both volcanic ash and desert dust in its iron fertilization potential." Global Biogeochemical Cycles.
Citation
Title  Geochemistry of sediments and volcanic ash from Southcentral Alaska
creation date 2020-09-17
publication date 2021
cited responsible party - author
individual Name  Koffman, Bess
No contact information provided.
cited responsible party - author
individual Name  Yoder, Meg
No contact information provided.
cited responsible party - author
individual Name  Methven, Taylor
No contact information provided.
cited responsible party - author
individual Name  Hanschka, Lena
No contact information provided.
cited responsible party - author
individual Name  Sears, Helen
No contact information provided.
cited responsible party - author
individual Name  Saylor, Patrick
No contact information provided.
cited responsible party - author
individual Name  Wallace, Kristi
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cited responsible party - publisher
organisation Name  Interdisciplinary Earth Data Alliance (IEDA)
No contact information provided.
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Resource language:   eng
Resource progress code:   Complete
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Creative Commons Attribution-ShareAlike 4.0 International [CC BY-SA 4.0]
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Creative Commons Attribution-ShareAlike 4.0 International [CC BY-SA 4.0]
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Classification  unclassified
Format
Format name  application/vnd.openxmlformats-officedocument.spreadsheetml.sheet
Format version  1.0
Resource extent
Extent description
Alaska
Geographic Extent
Sample Location (gmlPos):  60.8559 -137.1118
Sample Location (gmlPos):  61.5025 -149.0306
Sample Location (gmlPos):  61.5218 -144.3429
Sample Location (gmlPos):  61.522 -144.3263
Sample Location (gmlPos):  61.5347 -144.3787
Sample Location (gmlPos):  61.6057 -149.0709
Sample Location (gmlPos):  61.7882 -148.4472
Sample Location (gmlPos):  61.7953 -147.799
Sample Location (gmlPos):  62.3005 -135.3165
Sample Location (gmlPos):  62.3026 -145.3064
Sample Location (gmlPos):  62.3232 -150.1219
Sample Location (gmlPos):  62.3269 -150.1212
Sample Location (gmlPos):  62.4094 -145.0462
Sample Location (gmlPos):  62.6023 -144.6439
Sample Location (gmlPos):  62.6383 -144.5265
Sample Location (gmlPos):  62.6612 -144.4705
point of contact - pointOfContact
individual Name  Koffman, Bess
No contact information provided.
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URL: http://dx.doi.org/10.26022/IEDA/111679
protocol  WWW:LINK-1.0-http--link
link function  information
Description  Link to DOI landing page or data facility landing page if no DOI is assigned.
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name  URL
URL: https://ecl.earthchem.org/view.php?id=1679
protocol  WWW:LINK-1.0-http--link
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notes:  This metadata record was generated by an xslt transformation from a DataCite metadata record; The transform was created by Damian Ulbricht and Stephen M. Richard. 2017-11-15 these records include new IEDA keywords for geoportal facets Run on 2020-09-17T15:27:13-04:00
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organisation Name  Interdisciplinary Earth Data Alliance
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electronic Mail Address: info@iedadata.org
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URL: http://www.earthchem.org/sites/default/files/files/EC_0-1.png
link function  browseGraphic
Metadata scope code  dataset
Metadata hierarchy level name:  Dataset
Metadata language   eng
Metadata character set encoding:   utf8
Metadata standard for this record:  ISO 19139 Geographic Information - Metadata - Implementation Specification
standard version:  2007
Metadata record identifier:  urn:ieda:metadataabout:10.26022-IEDA-111679
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Metadata record format is ISO19139 XML (MD_Metadata)